Table 1. Enzymatic oxidation of (R)-limonene (1.0 mmol∙L-1) using HRP with direct additon of hydrogen peroxide. |
(R)-limonene |
H2O2 |
Stoichiometric |
(R)-limonene |
Conversion |
Observed |
mmol•L-1 |
mmol•L-1 |
mmol•L-1 |
mmol•L-1 |
% |
|
0.5 |
1 |
1:2 |
0.36 |
28.00 |
(S)-Carveol + (S)-Carvone (1:1) |
1 |
1 |
1:1 |
0.61 |
38.75 |
(S)-Carveol |
0.5 |
0.5 |
1:1 |
0.45 |
10.00 |
(S)-Carveol |
5 |
1 |
5:1 |
4.22 |
15.60 |
(S)-Carveol |
1 |
2 |
1:2 |
0.35 |
65.00 |
(S)-Carveol + (S)-Carvone (3:1) |
5 |
5 |
1:1 |
2.32 |
53.60 |
(S)-Carveol + (S)-Carvone (2:1) |
1 |
5 |
1:5 |
0.31 |
69.00 |
(S)-Carveol + (S)-Carvone (1:3) |
0.5 |
5 |
1:10 |
0.15 |
70.00 |
(S)-Carveol + (S)-Carvone (1:4) |
|