Table 2. Product distribution according to oxidation type: Electroenzymatic (EG CC), CO and electro oxidation (EG AC). |
Oxidation |
H2O2 |
Approximated |
Observed products/proportion |
|||
|
Aeration mode |
Electrode used |
mVSCE |
mmol•L-1 |
mmol•L-1 |
|
EG AC |
Continuous |
CW |
-620 |
- |
- |
(S)-Carveol |
EG CC |
Continuous |
CW |
-620 |
1.2 |
1:1.2 |
(S)-Carveol + (S)-Carvone (3:1) |
CO |
Continuous |
CW |
-620 |
1.2 |
1:1.2 |
(S)-Carveol |
EG AC |
Continuous |
RVCE |
-620 |
- |
- |
(S)-Carveol |
EG CC |
Continuous |
RVCE |
-620 |
0.35 |
3:1 |
(S)-Carveol |
CO |
Continuous |
RVCE |
-620 |
0.35 |
3:1 |
N.D. |
EG AC |
Discontonuous |
CW |
-620 |
- |
- |
(S)-Carveol |
EG CC |
Discontonuous |
CW |
-620 |
0.77 |
1.5:1 |
(S)-Carveol + (S)-Carvone (1:1) |
CO |
Discontonuous |
CW |
-620 |
0.77 |
1.5:1 |
(S)-Carveol |
EG AC |
Discontonuous |
RVCE |
-620 |
- |
- |
(S)-Carveol |
EG CC |
Discontonuous |
RVCE |
-620 |
0.25 |
4:1 |
(S)-Carveol |
CO |
Discontonuous |
RVCE |
-620 |
0.25 |
4:1 |
N.D. |
Note: All experiments contained (R)-limonene in an initial concentration of 1.0 mmol∙L-1 and acetone 30%. |
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