Table 4. The rate of improvement (RI in h-1) in the enantiomeric excess of the substrate and the fit of the estimating line expressed as the coefficient of determination, r2. The value of RI precedes the value of r2. |
Ibuprofen Concentration |
60 mM |
48 mM |
36 mM |
24 mM |
|
Isooctane |
aw = 0.73 |
0.0085 |
0.0077 |
0.0078 |
0.0086 |
aw = 0.59 |
0.0071 |
0.0068 |
0.0065 |
0.0063 |
|
aw = 0.43 |
0.0038 |
0.0039 |
0.0042 |
0.0045 |
|
2,5-Dimethylhexane |
aw = 0.73 |
0.0051 |
0.0041 |
0.0033 |
ND |
aw = 0.59 |
0.0032 |
0.0028 |
0.0021 |
ND |
|
aw = 0.43 |
NR |
NR |
NR |
ND |
|
2-Methylheptane |
aw = 0.73 |
0.0075 |
0.0074 |
0.0073 |
0.0073 |
aw = 0.59 |
0.0073 |
0.0067 |
0.0064 |
0.0059 |
|
aw = 0.43 |
0.0024 |
0.0037 |
0.0033 |
NR |
|
n-Octane |
aw = 0.73 |
0.0062 |
0.0057 |
0.0051 |
0.0060 |
aw = 0.59 |
0.0048 |
0.0051 |
0.0041 |
0.0042 |
|
aw = 0.43 |
0.0017 |
0.0020 |
0.0021 |
0.0025 |
ND:
indicates the reaction was not performed. |
|