Table 2. Kinetic values calculated according to the pseudo-first order, pseudo-second order and intra-particle diffusion kinetic models. |
Parameters |
Experimental |
Pseudo-first |
Pseudo-second |
Intra-particle |
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T |
Concentration |
pH |
qe |
qe |
k1 |
R2 |
qe |
k2 |
R2 |
kid1 |
R2 |
kid2 |
R2 |
40 |
1.0 |
6.0 |
1.65 x 10-4 |
1.04x10-4 |
1.15x10-3 |
0.9515 |
1.68x10-4 |
35.3 |
0.9927 |
2.0x10-6 |
0.9553 |
1.0x10-6 |
0.9898 |
40 |
1.5 |
6.0 |
2.24 x 10-4 |
1.97 x 10-4 |
1.15 x 10-3 |
0.9581 |
2.28 x 10-4 |
34.6 |
0.9976 |
4.0 x 10-6 |
0.9820 |
8.0 x 10-7 |
0,9862 |
40 |
2.0 |
6.0 |
2.67 x 10-4 |
1.39 x 10-4 |
9.21 x 10-4 |
0.9341 |
2,69 x 10-4 |
25.6 |
0.9953 |
4.0 x 10-6 |
0.9865 |
2.0 x 10-6 |
0,9964 |
40 |
2.5 |
6.0 |
3.06 x 10-4 |
2.34 x 10-4 |
1.61 x 10-3 |
0.9324 |
3.13 x 10-4 |
30.7 |
0.9987 |
6.0 x 10-6 |
0.9637 |
1.0 x 10-6 |
0.9190 |
40 |
3.0 |
6.0 |
3.19 x 10-4 |
1.89 x 10-4 |
1.15 x 10-3 |
0.9012 |
3.25 x 10-4 |
30.0 |
0.9987 |
6.0 x 10-6 |
0.9743 |
1.0 x 10-6 |
0.9311 |
30 |
2.0 |
6.0 |
2.57 x 10-4 |
1.52 x 10-4 |
9.21 x 10-4 |
0.9512 |
2,61 x 10-4 |
21.8 |
0.9927 |
3.0 x 10-6 |
0.9499 |
2.0 x 10-6 |
0.9467 |
20 |
2.0 |
6.0 |
2.51 x 10-4 |
1.74 x 10-4 |
1.15 x 10-3 |
0.9798 |
2,59 x 10-4 |
17.2 |
0.9912 |
4.0 x 10-6 |
0.9779 |
2.0 x 10-6 |
0.9786 |
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