Process Biotechnology

Electronic Journal of Biotechnology ISSN: 0717-3458 Vol. 6 No. 3, Issue of December 15, 2003
© 2003 by Pontificia Universidad Católica de Valparaíso -- Chile Received June 26, 2003 / Accepted December 5, 2003
RESEARCH ARTICLE

Optimisation of the solids suspension conditions in a continuous stirred tank reactor for the biooxidation of refractory gold concentrates

Ramón González§
Escuela de Ingeniería Bioquímica
Pontificia Universidad Católica de Valparaíso
Av. Brasil 2147, Valparaíso, Chile
Tel: 56 32 273647
Fax: 56 32 273803
E-mail: ramong@iastate.edu

Juan C. Gentina*
Escuela de Ingeniería Bioquímica
Pontificia Universidad Católica de Valparaíso
Av. Brasil 2147, Valparaíso, Chile
Tel: 56 32 273647
Fax: 56 32 273803
E-mail: jgentina@ucv.cl

Fernando Acevedo
Escuela de Ingeniería Bioquímica
Pontificia Universidad Católica de Valparaíso
Av. Brasil 2147, Valparaíso, Chile
Tel: 56 32 273644
Fax: 56 32 273803
E-mail: facevedo@ucv.cl

*Corresponding author


Financial support:
FONDECYT 1980335 and DGIP-UCV 203.780. One of them (RG) received a AGCI fellowship from the Chilean government.

Keywords: agitation, bioreactor, biooxidation, slurry.

Present address: § Department of Chemical Engineering, Iowa State University, Ames IA 50011-2230, USA. Tel: 1 515 294 1516; Fax: 1 515 294 2689.

Abbreviations:
C: Distance from the bottom of the reactor to the impeller;
CCR: Central composite rotatable experimental design;
CSTR: Continuous stirred tank reactor;
D: Impeller diameter;
HL: Fluid height in the tank;
HT: Total tank height;
h: Distance from bottom of the cylindrical section of the tank to the impeller;
J: Baffle width;

N: Agitation rate;
NP: Power number, P/·ρ N3·D5;
P: Ungassed agitation power;
RSM: Response surface methodology;
rpm: Revolutions per minute;
T: Tank diameter;
vvm: Volumes of air per volume of fluid per minute;
ρ: Fluid density;
3MPU: Three-blade marine propeller pumping up;
6MFU: Six-blade mixed flow turbine pumping up.


Abstract
Full Text

The large-scale biooxidation of gold concentrates is usually carried on in continuous stirred tank reactors (CSTR). Attaining homogeneous slurries is a difficult task, as solids tend to stratify in the tank. The objective of this work was to determine the optimal conditions of agitation in a CSTR so to obtain the best solids suspension. The experiments were performed in a 5 litre glass tank operated with 3 litres of 6% w/v slurry. The impellers (pitched blade turbine or marine propeller) were placed at heights of 6.7 to 13.4 cm from the bottom and operated at 370 to 1040 rpm, with specific aeration rates of 0.3 to 3.7 vvm. A statistical experimental design was used which allowed the derivation of a model representing response surfaces of the exit and mean solids concentration as a function of the impeller type, impeller distance from the bottom and aeration and agitation rates. During the experiments no solids were deposited on the bottom and the solids concentration near the bottom was always higher than that of the top region. At the optimal conditions for each type of impeller, the marine propeller required agitation rates about 15 to 22% higher than the pitched blade turbine. Nevertheless it is concluded that the marine helix is preferable because it requires less power and produces a more homogeneous suspension.

 
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