Environmental
Biotechnology |
Process
Biotechnology |
Electronic Journal of Biotechnology
ISSN: 0717-3458 |
Vol. 9 No. 2, Issue of April 15, 2006 |
© 2006 by Pontificia Universidad Católica
de Valparaíso -- Chile |
Received July 4, 2005 / Accepted October 17, 2005 |
DOI: 10.2225/vol9-issue2-fulltext-9 |
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Recovery
of lead and cadmium ions from metal-loaded biomass of wild cocoyam
(Caladium bicolor) using acidic, basic and neutral eluent
solutions
Michael Horsfall Jnr*
Department
of Pure and Industrial Chemistry
University of Port
Harcourt
P. O. Box
402, Choba
Port Harcourt, Nigeria
Tel: 234 803 507 9595
E-mail: horsfalljnr@yahoo.com
Fred
E. Ogban
Department of Chemistry
Delta State
University
P. M. B 1, Abraka
Delta State, Nigeria
Tel: 234-8025434425
Eyetemi
E. Akporhonor
Department of Chemistry
Delta State
University
P. M. B 1, Abraka
Delta State, Nigeria
Tel: 234-8035501947
*Corresponding
author
Financial
support: This project was sponsored by International Foundation
for Science (IFS) in collaboration with COMSTECH (The Committee on
Scientific and Technological Cooperation of the Organization of Islamic
Conference, Islamabad, Pakistan
and INWERDAM (Inter-Islamic Network on Water Resources Development
and Management, Amman,
Jordania) through Grant No. W/3624-1 to Dr M. Horsfall Jnr.
Keywords: cocoyam,
desorption, heavy metals removal, metal recovery, water treatment.
The effects of acidic,
basic and neutral reagents on the recovery of Pb2+ and
Cd2+ from metal-loaded biomass of wild cocoyam (C. bicolor)
were investigated by eluting the biomass in five successive cycles
using 0.01 M
HCl, 0.1 M
HCl, 0.01 M
NaOH, 0.1 M
NaOH and distilled water at different contact times. The data showed
that the ease of metal ion recovery from metal -loaded biomass by
the eluent solutions is of the order 0.01
M HCl > 0.1
M HCl > 0.01
M NaOH > 0.1
M NaOH > distilled water. Over 94% Pb2+
and 74% Cd2+ of the initially adsorbed metals were recovered
by 0.01 M HCl, while < 20% of both metals was recovered by basic
reagent. Distilled water recovered less than 9% of both metal ions
from the biomass. Macroscopic changes were also observed as the concentration
of recovery reagent increased. This study has demonstrated that the
selection of a recovery reagent for metal ions on a biomaterial should
give consideration to the reusability of the biomass.
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